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Different methods of synthesis Trichloroisocyanuric Acid (TCCA)

In a direct conversion of primary and secondary alcohols into the corresponding α-chloro aldehydes and α-chloro ketones, Trichloroisocyanuric Acid (TCCA) serves both as stoichiometric oxidant and α-halogenating reagent. For primary alcohols, TEMPO has to be added as an oxidation catalyst, and for the transformation of secondary alcohols MeOH as an additive is essential to promote chlorination of the intermediary ketones.
In a direct conversion of primary and secondary alcohols into the corresponding α-chloro aldehydes and α-chloro ketones, trichloroisocyanuric acid serves both as stoichiometric oxidant and α-halogenating reagent. For primary alcohols, TEMPO has to be added as an oxidation catalyst, and for the transformation of secondary alcohols MeOH as an additive is essential to promote chlorination of the intermediary ketones. An efficient and highly selective method for the oxidative conversion of primary amines to the corresponding nitriles using trichloroisocyanuric acid in the presence of catalytic TEMPO provides a new entry to the synthesis of various aliphatic, aromatic and heterocyclic nitriles in excellent yield.
An efficient one-pot conversion of various alcohols, aldehydes and primary amines into the corresponding nitriles in excellent yields was easily achieved by the use of trichloro-isocyanuric acid (TCCA) as an oxidant in aqueous ammonia. Also, various benzylic halides were smoothly and directly converted into the corresponding aromatic nitriles in high yields under the same conditions. A mild and metal-free method for the chlorodeboronation of organotrifluoroborates using trichloroisocyanuric acid (TCICA) converts aryl-, heteroaryl-, alkenyl-, alkynyl-, and alkyltrifluoroborates into the corresponding chlorinated products in good yields. This method tolerates a broad range of functional groups.
You can search Lookchem.com to buy Trichloroisocyanuric Acid (TCCA) . Characteristics of drugs: White crystalline powder or granular solid, with a strong chlorine odor stimulus, containing chlorine in more than 85%, the solubility in water of 1.2%, the case of acid or alkali decomposition. This product is a highly oxygen agent and a chlorinating agent, is an efficient, broad-spectrum, safer disinfection against bacteria, viruses, really, bacteria, spores and others, can kill coccidia oocysts.